For many people, the aroma of freshly brewed coffee is the start of a great day. But caffeine can cause headaches and jitters in others. That's why many people reach for a decaffeinated cup instead.

I'm a chemistry professor who has taught lectures on why chemicals dissolve in some liquids but not in others. The processes of decaffeination offer great real-life examples of these chemistry concepts. Even the best decaffeination method, however, does not remove all of the caffeine – about 7 milligrams of caffeine usually remain in an 8-ounce cup.

Producers decaffeinating their coffee want to remove the caffeine while retaining all – or at least most – of the other chemical aroma and flavor compounds. Decaffeination has a rich history, and now almost all coffee producers use one of three common methods.

All these methods, which are also used to make decaffeinated tea, start with green, or unroasted, coffee beans that have been premoistened. Using roasted coffee beans would result in a coffee with a very different aroma and taste because the decaffeination steps would remove some flavor and odor compounds produced during roasting.

In the relatively new carbon dioxide method, developed in the early 1970s, producers use high-pressure CO₂ to extract caffeine from moistened coffee beans. They pump the CO₂ into a sealed vessel containing the moistened coffee beans, and the caffeine molecules dissolve in the CO₂.

Once the caffeine-laden CO₂ is separated from the beans, producers pass the CO₂ mixture either through a container of water or over a bed of activated carbon. Activated carbon is carbon that's been heated up to high temperatures and exposed to steam and oxygen, which creates pores in the carbon. This step filters out the caffeine, and most likely other chemical compounds, some of which affect the flavor of the coffee.

These........

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